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Recycling Industry
Ziegler-Natta Catalyst For Propylene Polymerization
Introduction:
C-2 is the 2nd generation sorbitol based PP clarifying agent which gives excellent clarity, gloss and surface smoothness to the PP products. It also improves physical properties of PP products, such as heat resistance, stiffness, moisture barrier etc.
Chemical Name: (1,3:2,4)-diparamethylbenzylidene sorbitol (MDBS) CAS No.: 54686-97-4
Introduction
P-101 and P-201 are high performance catalysts for the production of polypropylene. The catalysts are Ti- Mg based, belonging to Ziegler-Natta 4th generation catalyst. The catalysts are developed and manufactured in China by China Catalyst Limited using the state-of-the-art technology.
P-101 and P-201 catalysts have excellent performance in propylene polymerization. These catalysts are designed for use in the Spheripol technology. They show low sensitivities to impurities or poisons contained in the monomers, and thus offer wide operating windows in the Spheripol processes.
P-101 and P-201 also give high activity and high stereoregularity. The polymer particles have good morphology and low fines.
Specification
Catalyst | P-101 |
P-201 |
|
Morphology |
Granular |
Spherical |
|
Average particle size (μm) |
12-25 |
45-65 |
|
Ti content (%) |
1.8-3.0 |
1.8-3.0 |
|
Mg content (%) |
16-20 |
16-20 |
|
Activity (g Polymer/g Cat.) |
40 |
45 |
|
Bulk Density, poured (kg/l) |
0.45 min |
0.45 min |
|
Polymer X.I (%) |
95.0-99.1 |
95.0-99.1 |
|
Application in process |
Spheripol |
Spheripol |
Application
P-101 and P-201 are designed for the production of homo, random and impact polypropylene in the bulk,gas phase and slurry processes.P-101 is designed as a drop-in catalyst to replace Lynx 1010 or GF2A. P-201 is designed as a drop-in catalyst to replace FT4S-M1.
Package: 80 kg net weight/steel drum under nitrogen protection.
Recommended Product Type and Operating Condition in Spheripol Process
Catalyst |
P-101 |
P-201 |
|
Product type |
Homo and Reco |
Homo, Raco and Heco |
|
External donor |
“C”, “D” or “P” |
“C”, “D” or “P” |
|
Co-catalyst |
TEAL |
TEAL |
|
Prepoly temperature (oC) |
20 |
20 |
|
Loop temperature (oC) |
70 – 80 |
70 – 80 |
|
Gas phase temperature (oC) |
- |
75 – 80 |
|
Slurry density (g/l) |
560 – 570 |
550 – 560 |
|
TEAL/Donor (mol/mol) |
20 – 150 |
4 – 100 |
Polymer Flake Properties Made from P-101 & P-201
Catalyst |
P-101 |
P-201 |
|
Melt flow rate, homo (dg/min) |
0.3 – 400 |
0.3 – 400 |
|
Melt flow rate, raco (dg/min) |
0.3 – 100 |
0.3 – 100 |
|
Melt flow rate, heco (dg/min) |
|
0.2 – 100 |
|
Maximum C2 content (%) |
2 in raco |
4 in raco, 12 in heco |
|
Flake particle size (mm) |
0.6 – 1.0 |
1.5 – 3.0 |
Polymer Properties Made from P-101 & P-201
Catalyst |
P-101 |
P-201 |
|
Flexural modulus (MPa) |
800 – 2250 |
600 – 2250 |
|
Izod Impact at 23oC (J/m) |
30 – 100 |
30 – 800 |
|
Melting temperature (oC) |
140 – 165 |
130 – 165 |
|
X.S. in homo (%w/w) |
94 – 99 |
94 – 99 |
|
P.I. from reactor |
3.5 – 5.0 |
3.5 – 5.0 |